Villarreal vs Napoli — prediction, probabilities and score Champions League · 13 Oct, 19:00 UTC Zort's model makes Villarreal the most likely winner against Napoli, at 45%. The most likely score is 2:1. Both teams to score is a 61% chance. Kick-off is 13 Oct, 19:00 UTC in the Champions League. PROBABILITIES: 1: 45% X: 25% 2: 30% PREDICTED: Villarreal to win (45%) SCORELINE: 2:1 BTTS: Yes 61% Method: odds from around 27 bookmakers, de-vigged with Shin's method, then a Poisson/Dixon-Coles model for scorelines. Free, published daily before kick-off. No claim is made that these win. Full page: https://zort-app.com/predictions/villarreal-vs-napoli-2026-10-13 All fixtures for this date: https://zort-app.com/predictions/2026-10-13